ALPHA-OXO-2-FURANACETONITRILE
- Name: ALPHA-OXO-2-FURANACETONITRILE
- CAS: 6047-91-2
- Purity: 99%
Details
Quality Manufacturer Supply High Purity 99% ALPHA-OXO-2-FURANACETONITRILE 6047-91-2 with Reasonable Price
- Molecular Formula: C6H3NO2
- Molecular Weight: 121.095
- Vapor Pressure: 1.13mmHg at 25°C
- Melting Point: 19-87℃
- Refractive Index: 1.498
- Boiling Point: 175.8 °C at 760 mmHg
- Flash Point: 60.1 °C
- PSA: 54.00000
- Density: 1.246 g/cm3
- LogP: 0.98588
ALPHA-OXO-2-FURANACETONITRILE(Cas 6047-91-2) Usage
InChI:InChI=1/C6H3NO2/c7-4-5(8)6-2-1-3-9-6/h1-3H
6047-91-2 Relevant articles
Rh-Catalyzed Asymmetric Hydrogenation of 1,2-Dicyanoalkenes
Li, Meina,Kong, Duanyang,Zi, Guofu,Hou, Guohua
, p. 680 - 687 (2017/04/26)
A highly efficient enantioselective hydr...
Detrifluoroacetylation of 4,4,4-trifluoro-3,3-dihydroxy-2-(hydroxyimino)butan-1-ones as a convenient synthetic strategy for acyl cyanides Dedicated to Academician Valery N. Charushin on his 65th birthday.
Bazhin, Denis N.,Kudyakova, Yulia S.,Nemytova, Natalia A.,Burgart, Yanina V.,Saloutin, Victor I.
, p. 28 - 32 (2016/05/02)
A reaction reinvestigation of fluorinate...
Reactions of Zirconocene-1-Aza-1,3-diene Complexes with Acyl Cyanides: Substrate-Dependent Synthesis of Acyl- or Non-Acyl-Substituted Pyrroles
Xiong, Meijun,Yu, Shasha,Xie, Xin,Li, Shi,Liu, Yuanhong
supporting information, p. 5597 - 5601 (2015/12/23)
Insertion of acyl cyanides into azazirco...
Conjugate hydrocyanation of aromatic enones using potassium hexacyanoferrate(II) as an eco-friendly cyanide source
Li, Zheng,Liu, Chenhui,Zhang, Yupeng,Li, Rongzhi,Ma, Ben,Yang, Jingya
supporting information, p. 2567 - 2571 (2012/11/13)
A selective conjugate hydrocyanation of ...
6047-91-2 Process route
-
-
527-69-5
2-furancarbonyl chloride
-
-
151-50-8
potassium cyanide
-
-
6047-91-2
2-furoyl cyanide
| Conditions | Yield |
|---|---|
|
With
zinc(II) iodide;
PEG400;
In
dichloromethane;
at 20 ℃;
for 5h;
|
86%
|
|
In
water; acetonitrile;
at 80 ℃;
for 1.5h;
|
78%
|
|
In
acetonitrile;
at 50 ℃;
for 1h;
ultrasound;
|
76%
|
|
With
AMBERLITE XAD-4;
In
water; benzene;
at 30 ℃;
for 2h;
|
73%
|
-
-
527-69-5
2-furancarbonyl chloride
-
-
6047-91-2
2-furoyl cyanide
| Conditions | Yield |
|---|---|
|
With
PEG-400; potassium iodide; silver(I) iodide;
In
N,N-dimethyl-formamide;
at 20 ℃;
for 9h;
|
86%
|
6047-91-2 Upstream products
-
527-69-5
2-furancarbonyl chloride
-
74-90-8
hydrogen cyanide
-
151-50-8
potassium cyanide
-
2179-92-2
tri-n-butyltin cyanide
6047-91-2 Downstream products
-
617-90-3
2-furancarbonitrile
-
88-14-2
2-furanoic acid
-
492-94-4
furil
-
31909-58-7
2-furoylacetonitrile
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